|
|
lignoceroyl-CoA + NADP+ <=> trans-lignocer-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-13308
|
|
|
|
(3R)-3-hydroxycerotoyl-CoA <=> trans-cerot-2-enoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-13305
|
|
|
|
(3R)-3-hydroxy-lignoceroyl-CoA <=> trans-lignocer-2-enoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-13304
|
|
|
|
malonyl-CoA + behenoyl-CoA + H+ <=> 3-oxo-lignoceroyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-13297
|
|
|
|
(3R)-3-hydroxybehenoyl-CoA <=> trans-docos-2-enoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-13303
|
|
|
|
behenoyl-CoA + NADP+ <=> trans-docos-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
BRENDA:
BR50149
KEGG:
R10828
MetaCyc:
RXN-13307
|
|
|
|
(3R)-3-hydroxybehenoyl-CoA + NADP+ <=> 3-oxobehenoyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-13299
|
|
|
|
(3R)-3-hydroxy-arachidoyl-CoA + NADP+ <=> 3-oxo-arachidoyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
BRENDA:
BS422183
MetaCyc:
RXN-13298
|
|
|
|
(3R)-3-hydroxy-arachidoyl-CoA <=> (2E)-eicosenoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-13302
|
|
|
|
(3R)-3-hydroxycerotoyl-CoA + NADP+ <=> 3-oxocerotoyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-13301
|
|
|
|
malonyl-CoA + lignoceroyl-CoA + H+ <=> 3-oxocerotoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-13296
|
|
|
|
malonyl-CoA + stearoyl-CoA + H+ <=> 3-oxo-arachidoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
BRENDA:
BS421527
MetaCyc:
RXN-13294
|
|
|
|
arachidoyl-CoA + NADP+ <=> (2E)-eicosenoyl-CoA + NADPH + H+
|
1.3.1.8
acyl-CoA dehydrogenase (NADP+)
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
–
|
|
BRENDA:
BS258628
MetaCyc:
RXN-13306
|
|
|
|
(3R)-3-hydroxy-lignoceroyl-CoA + NADP+ <=> 3-oxo-lignoceroyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
BRENDA:
BS422184
MetaCyc:
RXN-13300
|
|
|
|
malonyl-CoA + arachidoyl-CoA + H+ <=> 3-oxobehenoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-13295
|
|
|
|
hexacosanoyl-CoA + NADP+ <=> trans-cerot-2-enoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-13309
|
|